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As we previously mentioned, upstart is a replacement for the init daemon upstart works using the notion of jobs (or tasks) and events Jobs are created and placed under the /etc/eventd/ directory The name of the job is the filename under this directory To transparently handle the services that were hitherto handled by init, jobs have been defined to handle the services and daemons that need to be started and stopped at the various runlevels (0,1,2,3,4,5,6,S, etc) For example, the job definition that automatically handles the services that are to be started at runlevel 3 is defined in a file named: /etc/eventd/rc3 The contents of the file looks like this:

4 ~L McGlashan and R P Rastogi, Tmns Faraday Soc, vol 54, p 496, 1958

Figure 126 The chloroform(l)/l,4-dioxane(2) system at 32315 K (50 C) (a) Pxy data and their correlation (b) Liquid-phase properties and their correlation

# rc3 - runlevel 3 compatibility # This task runs the old sysv-rc runlevel 3 (user defined) scripts # is usually started by the telinit compatibility wrapper start on runlevel 3 stop on runlevel console output script set $(runlevel --set 3 || true) if [ "$1" != "unknown" ]; then PREVLEVEL=$1 RUNLEVEL=$2 export PREVLEVEL RUNLEVEL fi exec /etc/rcd/rc 3 end script It

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that the Margules equations are not precisely suited to the data set; second, that the P-xl-yl data themselves are systematically in error such that they do not conform to the requirements of the GibbsDuhem equation We have presumed in applying the Margules equations that the deviations of the experimental points for G E / x 1 x 2 f ~ the straight lines drawn to represent them result from from random error in the data Indeed, the straight lines do provide excellent correlations of all but a few data points Only toward edges of a diagram are there significant deviations, and these have been discounted, because the error bounds widen rapidly as the edges of a diagram are approached In the limits as xl -+ 0 and xl + 1, G ~ / X ~ Xbecomes indeterminate; ex~RT perimentally this means that the values are subject to unlimited error and are not measurable However, tlie possibility exists that the correlation would be improved were the G E / x I x 2 R T points represented by an appropriate curve Finding the correlation that best represents the data is a trial procedure

Without going into too much detail, the previous job definition can be explained as follows: The start stanza specifies that the job be run during the occurrence of an event The event in this case is the system entering runlevel 3 The stop stanza specifies that the job be stopped during the occurrence of an event The script stanza specifies the shell script code that will be executed using /bin/sh The exec stanza specifies the path to a binary on the file system and optional arguments to pass to it You can query the status of any job by using the status command For example, to query the status of our example rc3 job, run

The GibbsDuhem equation imposes a constraint on activity coefficients that may not be satisfied by experimental values containing systematic error If this is the case, the experimental 2 T values of In yl and In y used for calculation of G E / ~ by Eq (126), which does not depend

The initctl command can be used to display a listing of all jobs and their states For example, to list all jobs and their states, run

on the GibbsDuhem equation, will not agree with values of In yl and In y2 later calculated by equations derived from Eq (1 192), which does implicitly contain the GibbsDuhem equation No correlating equation exists that can then precisely represent the original P-xl-yl data Such data are said to be inconsistent with the Gibbsmuhem equation, and are necessarily incorrect Our purpose now is to develop a simple test for the consistency with respect to the GibbsDuhem equation of a P-xl-yl data set Equation (126) is written with experimental values, calculated by (Eq 121), and denoted by an asterisk:

The /etc/inittab file contains all the information init needs for starting runlevels The format of each line in this file is as follows:

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