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from which they started The main mechanism by which daemons can interface with the rest of the system is through interprocess communication (IPC) channels, by sending messages to the system-wide log file, or by appending to a file on disk The role of inetd is to function as a super-server to other network server related processes, such as telnet, ftp, tftp, etc It s a simple philosophy: Not all server processes (including those that accept new connections) are called upon so often that they require a program to be running in memory all the time The main reason for the existence of a super-server is to conserve system resources So instead of constantly maintaining potentially dozens of services loaded in memory waiting to be used, they are all listed in inetd s configuration file, /etc/inetdconf On their behalf, inetd listens for incoming connections Thus, only a single process needs to be in memory A secondary benefit of inetd falls to those processes needing network connectivity but whose programmers do not want to have to write it into the system The inetd program will handle the network code and pass incoming network streams into the process as its standard input (stdin) Any of the process s output (stdout) is sent back to the host that has connected to the process NOTE Unless you are programming, you don t have to be concerned with inetd s stdin/ stdout feature On the other hand, for someone who wants to write a simple script and make it available through the network, it s worth exploring this powerful tool As a general rule of thumb, low-volume services (such as tftp) are usually best run through the inetd, whereas higher-volume services (such as web servers) are better run as a stand-alone process that is always in memory, ready to handle requests Current versions of Fedora, Red Hat Enterprise Linux (RHEL), OpenSuSE, Mandrake, and even Mac OS X ship with a newer incarnation of inetd called xinetd the name is an acronym for extended Internet services daemon The xinetd program accomplishes the same task as the regular inetd program: It helps to start programs that provide Internet services Instead of having such programs automatically start up during system initialization and remain unused until a connection request arrives, xinetd instead stands in the gap for those programs and listens on their normal service ports As a result, when xinetd hears a service request meant for one of the services it manages, it then starts or spurns the appropriate service Inasmuch as xinetd is similar to inetd in function, it should be noted that it includes a new configuration file format and a lot of additional features The xinetd daemon uses a configuration file format that is quite different from the classic inetd configuration file format (Most other variants of UNIX, including Solaris, AIX, and FreeBSD, use the classic inetd format) This means that if you have an application that relies on inetd, you may need to provide some manual adjustments to make it work Of course, you should definitely contact the developers of the application and let them know of the change so that they can release a newer version that works with the new xinetd configuration format as well.

Figure 129 shows plots of In yi based on experimental measurements for six binary systems at 32315 K (50 C), illustrating the variety of behavior that is observed Note in every case that as xi + 1, In yi -+ 0 with zero slope Usually (but not always) the infinite-dilution activity coefficient is an extreme value Comparison of these graphs with those of Fig 114 indicates that the In yi generally have the same sign as G E That is, positive G Eimplies activity coefficients greater than unity and negative G E implies activity coefficients less than unity, at least over most of the composition range

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In this section, we will cover the new xinetd daemon If your system uses inetd, you should be able to view the /etc/inetdconf file and see the similarities between inetd and xinetd NOTE Your Linux distribution might not have the xinetd software installed out of the box The xinetd package can be installed with yum on a Fedora distro (or RHEL, Centos) by running

s ~A Barker,Austral J Chem, vol 6, pp 207-210, 1953

The /etc/xinetdconf file consists of a series of blocks that take the following format:

Figure 129 Logarithms of the activity coefficients at 32315 K (50 C) for six binary liquid systems: (a) chloroform(l)ln-heptane(2); (b) acetone(l)/methanol(2); ( c ) acetone(l)lchloroform(2); ( d ) ethanol(1)ln-heptane(2); (e) ethanol(l)/chloroform(2); ( f ) ethanol(l)/water(2)

blockname { variable = value }

In general G E /RT is a function of T, P, and composition, but for liquids at low to moderate pressures it is a very weak function of P Therefore the pressure dependence of activity coefficients is usually neglected Thus, for data at constant T :

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